Effect of cyclodextrins on the rhodium-catalysed hydrogenation of unsaturated carboxylic acids in water

被引：12

作者：

Arzoumanian, H ^{[1
]}

Nuel, D ^{[1
]}

机构：

[1] ENSSPICAM, Fac St Jerome, UMR CNRS 6516, F-13397 Marseille 20, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 5-6期

关键词：

aqueous medium; cyclodextrin; selective hydrogenation;

D O I：

10.1016/S1387-1609(00)88537-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of cyclodextrin to the well-known RhCl3/TPPTS (trisulfonated triphenylphosphine) hydrogenation catalytic system leads to high selectivities in the hydrogenation of unsaturated carboxylic acids in water. The presence of both cyclodextrin and sulfonate ions is required to obtain high selectivities. (C) Academie des sciences/Elsevier, Paris.

引用

页码：289 / 293

页数：5

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