Mechanistic aspects of the hydrogenation of some unsaturated mono and diacids and their methyl esters

被引：10

作者：

Bucsai, A

Bakos, J

Laghmari, M

Sinou, D

机构：

[1] UNIV LYON 1,CPE LYON,CNRS,LAB SYNTH ASYMETR,F-69622 VILLEURBANNE,FRANCE

[2] UNIV VESZPREM,DEPT ORGAN CHEM,H-8201 VESZPREM,HUNGARY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 116卷 / 03期

基金：

匈牙利科学研究基金会;

关键词：

unsaturated diesters; rhodium complexes; reduction; deuterium; beta-elimination;

D O I：

10.1016/S1381-1169(96)00367-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The study of the reduction of some unsaturated diesters under a deuterium atmosphere shows that beta-elimination is a very fast process compared to the reductive elimination. This allows the introduction of deuterium atoms at position alpha of the double bond and the addition of hydrogen atoms on the double bond.

引用

收藏

页码：335 / 342

页数：8

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