Enantioselective adsorption of ferrocene-modified glutamic acids on helical poly(L-glutamic acid) self-assemblies at gold electrodes

被引：10

作者：

Niwa, M

Matsui, M

Koide, K

Higashi, N

机构：

[1] Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 11期

关键词：

D O I：

10.1039/a704134i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel poly(L-glutamic acid) (PLGA) self-assembled monolayer was prepared on an Au electrode. The conformational transition of the PLGA segment between alpha-helix and coil could be electrochemically monitored by use of a redox couple of Fe(CN)(6)(3-/4-). The helical PLGA monolayer was found to capture ferrocene-modified glutamic acids enantiomerically by means of an electron transfer reaction of the surface-confined ferrocenyl moiety.

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收藏

页码：2191 / 2192

页数：2

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