A novel 3D polyoxometalate-linked polypseudo-rotaxane framework by using semi-rigid bis(triazole) ligand

被引：7

作者：

Wang, Xiuli ^{[1
]}

Liu, Xiaojing ^{[1
]}

Tian, Aixiang ^{[1
]}

Ying, Jun ^{[1
]}

Lin, Hongyan ^{[1
]}

Liu, Guocheng ^{[1
]}

Zhang, Juwen ^{[1
]}

Zhao, Dan ^{[1
]}

机构：

[1] Bohai Univ, Dept Chem, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Jinzhou 121000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 17卷

关键词：

Keggin polyoxometalate; Hydrothermal synthesis; Semi-rigid bis(triazole) ligand; Polypseudo-rotaxane; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMER; POLYCATENATION; COMPLEXES;

D O I：

10.1016/j.inoche.2011.12.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 3D polyoxometalate-linked polypseudo-rotaxane framework, [Cu(L)(2)((HPW10W2O40)-W-VI-O-V)][Cu(L)(H2O)(4)]center dot 4H(2)O (1) (L=4,4'-bis(1,2,4-triazol-1-ylmethyl)biphenyl), was synthesized under hydrothermal conditions. Compound 1 contains a 2D grid-like sheet, which is constructed from bi-nuclear [Cu2L2](4+) cycles and Keggin anion linkages. The 1D polymeric [CuL(H2O)(4)](2+) chains penetrate the 2D sheets at an inclined angle to generate an interesting 3D polypseudo-rotaxane architecture. (c) 2011 Elsevier B.V. All rights reserved.

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收藏

页码：71 / 74

页数：4

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