Photocurrent Enhancement in Polythiophene- and Alkanethiol-Modified ZnO Solar Cells

被引:115
作者
Monson, Todd C. [1 ]
Lloyd, Matthew T. [1 ]
Olson, Dana C. [1 ]
Lee, Yun-Ju [1 ]
Hsu, Julia W. P. [1 ]
机构
[1] Sandia Natl Labs, Albuquerque, NM 87185 USA
关键词
D O I
10.1002/adma.200801082
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photocurrent enhancement and improvement in solar cell performance are found when the interface between ZnO and polythiophene layers is modified with insulating alkanethiol self-assembled monolayers. This result is correlated with increased structural order in the polymer and interchain contributions in the photocurrent, suggesting that improved exciton diffusion or reduced electron-hole recombination can outweigh the impedance in electron transfer at the heterojunction interface.
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页码:4755 / +
页数:6
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