Homogeneous cis-dihydroxylation and epoxidation of olefins with high H2O2 efficiency by mixed manganese/activated carbonyl catalyst system

被引：89

作者：

Brinksma, J

Schmieder, L

van Vliet, G

Boaron, R

Hage, R

De Vos, DE

Alsters, PL

Feringa, BL

机构：

[1] Univ Groningen, Stratingh Inst, Organ Chem Lab, NL-9747 AG Groningen, Netherlands

[2] DSM Fine Chem Adv Synth & Catalysis, NL-6160 MD Geleen, Netherlands

[3] Unilever Res Labs Vlaardingen, NL-3130 AC Vlaardingen, Netherlands

[4] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 14期

关键词：

hydrogen peroxide; cis-diols; epoxides; manganese; oxidation;

D O I：

10.1016/S0040-4039(02)00292-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of [Mn2O3(tmtacn)(2)](PF6)(2) (tmtacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) in combination with glyoxylic acid methylester methyl hemiacetal (GMHA) results in a highly active and hydrogen peroxide efficient catalyst for the epoxidation of olefins as well as the first homogeneous catalytic cis-dihydroxylation system with H2O2 and with turnover numbers up to 420. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2619 / 2622

页数：4

共 27 条

[21] Highly efficient epoxidation of olefins using aqueous H2O2 and catalytic methyltrioxorhenium/pyridine: Pyridine-mediated ligand acceleration [J].