Electrochemical/Mechanical Coupling in Ion-Conducting Soft Matter

被引:34
作者
Kusoglu, Ahmet [1 ]
Weber, Adam Z. [1 ]
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Energy Storage & Distributed Resources Div, Berkeley, CA 94720 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2015年 / 6卷 / 22期
关键词
POLYMER ELECTROLYTE MEMBRANE; PROTON-EXCHANGE MEMBRANES; SULFONIC-ACID MEMBRANE; FUEL-CELL MEMBRANES; CHEMICAL DEGRADATION; MECHANICAL-BEHAVIOR; GAS-CROSSOVER; FATIGUE; HUMIDITY; PERFORMANCE;
D O I
10.1021/acs.jpclett.5b01639
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mechanical and electrochemical phenomena exhibit many interesting multidirectional couplings in ion-exchange soft matter due to their intrinsic material physiochemical states and responses to environmental stressors. In this Perspective, such coupling is explored in terms of recent studies with a focus on the degradation of polymer-electrolyte fuel-cell membranes. In addition, (electro)chemical-mechanical coupling of ion-conducting polymers in other applications is also introduced, as there is a research need to explore the interactions between these often wrongly assumed disparate fields in order to optimize, exploit, and discover new technologies and applications.
引用
收藏
页码:4547 / 4552
页数:6
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