A Reversible and Higher-Rate Li-O2 Battery

被引：1708

作者：

Peng, Zhangquan ^{[1
]}

Freunberger, Stefan A. ^{[1
]}

Chen, Yuhui ^{[1
]}

Bruce, Peter G. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

SCIENCE | 2012年 / 337卷 / 6094期

基金：

英国工程与自然科学研究理事会;

关键词：

LITHIUM-OXYGEN BATTERY; LI-AIR BATTERIES; CARBONATE ELECTROLYTES; ELECTROCHEMISTRY; SOLVENTS; LIQUID; ETHER; O-2;

D O I：

10.1126/science.1223985

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The rechargeable nonaqueous lithium-air (Li-O-2) battery is receiving a great deal of interest because, theoretically, its specific energy far exceeds the best that can be achieved with lithium-ion cells. Operation of the rechargeable Li-O-2 battery depends critically on repeated and highly reversible formation/decomposition of lithium peroxide (Li2O2) at the cathode upon cycling. Here, we show that this process is possible with the use of a dimethyl sulfoxide electrolyte and a porous gold electrode (95% capacity retention from cycles 1 to 100), whereas previously only partial Li2O2 formation/decomposition and limited cycling could occur. Furthermore, we present data indicating that the kinetics of Li2O2 oxidation on charge is approximately 10 times faster than on carbon electrodes.

引用

页码：563 / 566

页数：4

共 32 条

[11] Investigation of the O2 Electrochemistry in a Polymer Electrolyte Solid-State Cell [J].

Hassoun, Jusef ;

Croce, Fausto ;

Armand, Michel ;

Scrosati, Bruno .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (13) :2999-3002

[12] Communications: Elementary oxygen electrode reactions in the aprotic Li-air battery [J].

Hummelshoj, J. S. ;

Blomqvist, J. ;

Datta, S. ;

Vegge, T. ;

Rossmeisl, J. ;

Thygesen, K. S. ;

Luntz, A. C. ;

Jacobsen, K. W. ;

Norskov, J. K. .

JOURNAL OF CHEMICAL PHYSICS, 2010, 132 (07)

[13]

Jung HG, 2012, NAT CHEM, V4, P579, DOI [10.1038/nchem.1376, 10.1038/NCHEM.1376]

[14] Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium-Air Battery [J].

Laoire, Cormac O. ;

Mukerjee, Sanjeev ;

Abraham, K. M. ;

Plichta, Edward J. ;

Hendrickson, Mary A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (19) :9178-9186

[15] Catalytic Activity Trends of Oxygen Reduction Reaction for Nonaqueous Li-Air Batteries [J].

Lu, Yi-Chun ;

Gasteiger, Hubert A. ;

Shao-Horn, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (47) :19048-19051

[16] The discharge rate capability of rechargeable Li-O2 batteries [J].

Lu, Yi-Chun ;

Kwabi, David G. ;

Yao, Koffi P. C. ;

Harding, Jonathon R. ;

Zhou, Jigang ;

Zuin, Lucia ;

Shao-Horn, Yang .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (08) :2999-3007

[17] Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li-O2 Batteries [J].

McCloskey, B. D. ;

Speidel, A. ;

Scheffler, R. ;

Miller, D. C. ;

Viswanathan, V. ;

Hummelshoj, J. S. ;

Norskov, J. K. ;

Luntz, A. C. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (08) :997-1001

[18] Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry [J].

McCloskey, B. D. ;

Bethune, D. S. ;

Shelby, R. M. ;

Girishkumar, G. ;

Luntz, A. C. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (10) :1161-1166

[19] On the Efficacy of Electrocatalysis in Nonaqueous Li-O2 Batteries [J].

McCloskey, Bryan D. ;

Scheffler, Rouven ;

Speidel, Angela ;

Bethune, Donald S. ;

Shelby, Robert M. ;

Luntz, A. C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (45) :18038-18041

[20] Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes [J].

Mizuno, Fuminori ;

Nakanishi, Shinji ;

Kotani, Yukinari ;

Yokoishi, Shoji ;

Iba, Hideki .

ELECTROCHEMISTRY, 2010, 78 (05) :403-405

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