Polyethylene glycol as a non-ionic liquid solvent for polyoxometalate catalyzed aerobic oxidation

被引：170

作者：

Haimov, A ^{[1
]}

Neumann, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 08期

关键词：

D O I：

10.1039/b200559j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H5PV2Mo10O40 polyoxometalate in a polyethylene glycol solvent was effective for a series of aerobic oxidation reactions including oxydehydrogenation of alcohols and cyclic dienes, oxidation of sulfides and the Wacker reaction; the solvent-catalyst phase can be recovered and recycled.

引用

页码：876 / 877

页数：2

共 20 条

[11] Khenkin AM, 2000, ANGEW CHEM INT EDIT, V39, P4088
[12] MATVEEV KI, 1977, KINET CATAL+, V18, P716
[13] AROMATIZATION OF HYDROCARBONS BY OXIDATIVE DEHYDROGENATION CATALYZED BY THE MIXED ADDENDA HETEROPOLY ACID H5PMO10V2O40
NEUMANN, R
LISSEL, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (19) : 4607 - 4610
[14] SELECTIVE AEROBIC OXIDATIVE DEHYDROGENATION OF ALCOHOLS AND AMINES CATALYZED BY A SUPPORTED MOLYBDENUM VANADIUM HETEROPOLYANION SALT NA5PMO2V2O40
NEUMANN, R
LEVIN, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (19) : 5707 - 5710
[15] Neumann R, 1998, PROG INORG CHEM, V47, P317
[16] The use of supercritical fluids in synthetic organic chemistry
Oakes, RS
Clifford, AA
Rayner, CM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (09): : 917 - 941
[17] Okuhara T, 1996, ADV CATAL, V41, P113, DOI 10.1016/S0360-0564(08)60041-3
[18] Catalytic reactions in ionic liquids
Sheldon, R
[J]. CHEMICAL COMMUNICATIONS, 2001, (23) : 2399 - 2407
[19] ten Brink GJ, 2000, SCIENCE, V287, P1636
[20] INDUSTRIAL-SCALE OXO SYNTHESIS WITH AN IMMOBILIZED CATALYST
WIEBUS, E
CORNILS, B
[J]. CHEMIE INGENIEUR TECHNIK, 1994, 66 (07) : 916 - 923

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