Electrochemical formation and composition analysis of ZnxCd1-xSe solid solutions

被引：10

作者：

Bouroushian, M ^{[1
]}

Kosanovic, T ^{[1
]}

机构：

[1] Natl Tech Univ Athens, Sch Chem Engn, Gen Chem Lab, Athens 15780, Greece

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2006年 / 10卷 / 04期

关键词：

zinc-cadmium-selenide; electrodeposition; X-ray diffraction; solid solutions;

D O I：

10.1007/s10008-005-0670-x

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The direct growth of ZnSe-CdSe solid solution onto metallic cathodes by electrodeposition from acidic aqueous sulphate solutions is described. The plating process is studied by simple voltammetry, while the structure and composition of the electrolytic deposits are investigated by X-ray diffraction. The experimental d-spacing values of the as-grown mixed lattice are compared to data from reference Zn (x) Cd1-x Se pellets of standard composition, produced by a sintering method. The findings are supplemented with energy-dispersive X-ray (EDX) elemental analysis. Thereupon, the variation of the mole fraction x in Zn (x) Cd1-x Se, and the solid phase constitution of the electrodeposits are determined and correlated to the electrochemical conditions of growth. The resulting films contain admixtures of CdSe compound and metallic Cd.

引用

页码：223 / 229

页数：7

共 18 条

[1] Electrochemical formation of Se atomic layers on Au(111) surfaces: the role of adsorbed selenate and selenite [J].

Alanyalioglu, M ;

Demir, U ;

Shannon, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 561 (1-2) :21-27

[2] RAMAN-SPECTROSCOPY OF 2 NOVEL SEMICONDUCTORS AND RELATED SUPERLATTICES - CUBIC CD1-XMNXSE AND CD1-XZNXSE [J].

ALONSO, RG ;

SUH, EK ;

RAMDAS, AK ;

SAMARTH, N ;

LUO, H ;

FURDYNA, JK .

PHYSICAL REVIEW B, 1989, 40 (06) :3720-3728

[3] Structural and optical properties of ZnxCd1-xSe thin films [J].

Ammar, AH .

PHYSICA B, 2001, 296 (04) :312-318

[4] Optical phonons in ZnxCd1-xSe thin films [J].

AvendanoLopez, J ;

CastilloAlvarado, FL ;

EscamillaEsquivel, A ;

ContrerasPuente, G ;

OrtizLopez, J ;

ZelayaAngel, O .

SOLID STATE COMMUNICATIONS, 1996, 100 (01) :33-36

[5] Electrochemical formation of zinc selenide from acidic aqueous solutions [J].

Bouroushian, M ;

Kosanovic, T ;

Loizos, Z ;

Spyrellis, N .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2002, 6 (04) :272-278

[6] On a thermodynamic description of Se(IV) electroreduction and CdSe electrolytic formation on Ni, Ti and Pt cathodes in acidic aqueous solution [J].

Bouroushian, M ;

Kosanovic, T ;

Loizos, Z ;

Spyrellis, N .

ELECTROCHEMISTRY COMMUNICATIONS, 2000, 2 (04) :281-285

[7] PHONONS AND STRUCTURE OF ZN CD1-XSE SOLID-SOLUTION [J].

BRAFMAN, O .

SOLID STATE COMMUNICATIONS, 1972, 11 (03) :447-+

[8] ELECTRODEPOSITION OF CD-ZN-SE THIN-FILMS FROM SELENOSULPHITE SOLUTIONS [J].

DARKOWSKI, A ;

GRABOWSKI, A .

SOLAR ENERGY MATERIALS, 1991, 23 (01) :75-82

[9] PREPARATION OF THIN-FILMS OF POLYCRYSTALLINE CDSE FOR SOLAR-ENERGY CONVERSION .1. A LITERATURE SURVEY [J].

GRUSZECKI, T ;

HOLMSTROM, B .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1993, 31 (02) :227-234

[10] OPTICAL-PROPERTIES OF ZNXCD1-X SE FILMS [J].

GUPTA, P ;

MAITI, B ;

MAITY, AB ;

CHAUDHURI, S ;

PAL, AK .

THIN SOLID FILMS, 1995, 260 (01) :75-85

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