Camphor-based beta-hydroxyphosphoryl ligands and their complexes of the type [MoO(O-2)(2)L(H2O)]

被引：11

作者：

Cross, RJ

Farrugia, LJ

Newman, PD

Peacock, RD

Stirling, D

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期

关键词：

D O I：

10.1039/dt9960004149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homochiral hydroxyphosphoryl compounds, L, such as-the novel camphor-based(1R)-endo, endo-3S-(diphenylphosphoryl)-2R-hydroxybornane, have been found to be prevented from behaving as bidentate ligands in the epoxidation catalysts [MoO(O-2)(2)L(H2O)] by unexpectedly strong multiple-bond delocalisation producing near linear Mo-O-P angles.

引用

页码：4149 / 4150

页数：2