H2 production through steam reforming of ethanol over Pt/ZrO2, Pt/CeO2 and Pt/CeZrO2 catalysts

被引：60

作者：

de Lima, Sania M. ^{[1
]}

Silva, Adriana M. ^{[1
]}

da Cruz, Ivna O. ^{[1
]}

Jacobs, Gary ^{[2
]}

Davis, Burtron H. ^{[2
]}

Mattos, Lisiane V. ^{[1
]}

Noronha, Fabio B. ^{[1
]}

机构：

[1] INT, BR-20081312 Rio De Janeiro, Brazil

[2] Univ Kentucky, Ctr Appl Energy Res, Lexington, KY 40511 USA

来源：

CATALYSIS TODAY | 2008年 / 138卷 / 3-4期

关键词：

Fuel cell; Hydrogen production; Steam reforming of ethanol; Pt catalysts;

D O I：

10.1016/j.cattod.2008.06.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The effect of the support nature and metal dispersion on the performance of Pt catalysts during steam reforming of ethanol was studied. H-2 and CO production was facilitated over Pt/CeO2 and Pt/CeZrO2, whereas the acetaldehyde and ethene formation was favored on Pt/ZrO2. According to the reaction mechanism, determined by temperature-programmed desorption (TPD) and Diffuse Reflectance Infrared Spectroscopy (DRIFTS) analysis, some reaction pathways are favored depending on the Support nature, which can explain the differences observed oil the resulting product distribution. (C) 2008 Elsevier B.V. All rights reserved.

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页码：162 / 168

页数：7

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