Selective ring opening cross metathesis of cyclooctadiene and trisubstituted cycloolefins

被引:56
作者
Morgan, JP [1 ]
Morrill, C [1 ]
Grubbs, RH [1 ]
机构
[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Lab Chem Synth, Pasadena, CA 91125 USA
关键词
D O I
10.1021/ol016918s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The selective ring opening cross metathesis of 1,5-cyclooctadiene and trisubstituted cycloolefins with acroyl species is described. The ring-opened products contain electronically differentiated olefins suitable for additional metathesis reactions. Trisubstituted cycloolefins open regioselectively, placing the acroyl cap on the less-substituted terminus.
引用
收藏
页码:67 / 70
页数:4
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