Optimization of experimental parameters and procedures for fluorescence excitation spectroscopy

被引：16

作者：

Cheatham, CM ^{[1
]}

Huang, MH ^{[1
]}

Laane, J ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1996年 / 377卷 / 01期

关键词：

fluorescence spectroscopy; supersonic jet; instrumentation;

D O I：

10.1016/0022-2860(95)09114-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The critical experimental parameters necessary to obtain fluorescence excitation spectra of weakly fluorescing samples are presented, and the methods necessary for their determination are discussed. Details relating to experimental timing, optical alignment, supersonic jet operation, and nozzle design are of special importance.

引用

收藏

页码：93 / 99

页数：7

相关论文

共 19 条

[11] A HIGH INTENSITY SOURCE FOR THE MOLECULAR BEAM .1. THEORETICAL [J].

KANTROWITZ, A ;

GREY, J .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1951, 22 (05) :328-332

[12] LASER SPECTROSCOPY OF COLD GAS-PHASE MOLECULES [J].

LEVY, DH .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1980, 31 :197-225

[13]

LEVY DH, 1977, CHEM BIOCH APPLICATI, V2, P1

[14] FLUORESCENCE EXCITATION SPECTRUM OF THE 1AU (NPI-]) ]-1AG (O-O) BAND OF OXALYL FLUORIDE IN A PULSED SUPERSONIC FREE JET [J].

LIVERMAN, MG ;

BECK, SM ;

MONTS, DL ;

SMALLEY, RE .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) :192-198

[15] FLUORESCENCE EXCITATION SPECTRUM OF HEL-2 VANDERWAALS COMPLEX [J].

SMALLEY, RE ;

LEVY, DH ;

WHARTON, L .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (08) :3266-3276

[16] MOLECULAR OPTICAL SPECTROSCOPY WITH SUPERSONIC BEAMS AND JETS [J].

SMALLEY, RE ;

WHARTON, L ;

LEVY, DH .

ACCOUNTS OF CHEMICAL RESEARCH, 1977, 10 (04) :139-145

[17] TORSIONAL BAND ASSIGNMENT AND INTRAMOLECULAR TWIST POTENTIAL OF 9,9'-BIANTHRYL AND ITS 10-CYANO DERIVATIVE IN A FREE JET [J].

SUBARICLEITIS, A ;

MONTE, C ;

ROGGAN, A ;

RETTIG, W ;

ZIMMERMANN, P ;

HEINZE, J .

JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (07) :4543-4555

[18] PHOSPHORESCENCE EXCITATION SPECTROSCOPY IN SUPERSONIC JETS - THE LOWEST TRIPLET-STATE OF PYRAZINE [J].

TOMER, JL ;

HOLTZCLAW, KW ;

PRATT, DW ;

SPANGLER, LH .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (03) :1528-1538

[19]

WARREN J, 1991, COMMUNICATION