Organopalladium(IV) chemistry

被引：623

作者：

Xu, Ling-Min

Li, Bi-Jie

Yang, Zhen

Shi, Zhang-Jie ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 02期

关键词：

C-H ACTIVATION; ALKYLATION-ALKENYLATION REACTIONS; N BOND FORMATION; INTERMOLECULAR DIRECT ARYLATION; PALLADIUM-CATALYZED SYNTHESIS; BIDENTATE NITROGEN LIGANDS; CROSS-COUPLING REACTIONS; REDUCTIVE ELIMINATION; OXIDATIVE ADDITION; ARYL-ARYL;

D O I：

10.1039/b809912j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although the chemistry of Pd(0), Pd(I) and Pd(II) is well established, high oxidation state Pd(IV) complexes are less well-known. This situation has highly changed in recent years. Many well-defined Pd(IV) complexes has been isolated and characterized, providing evidence for a series of proposed Pd(II)/Pd(IV) catalytic reactions. A deep understanding of the behavior of Pd(IV) complexes could lead to the design and development of novel reactions that could not be accessed by traditional Pd(0)/Pd(II) chemistry. This critical review describes the stoichiometric reactions of Pd(IV) complexes and discusses their potential mechanism in catalytic reactions (137 references).

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页码：712 / 733

页数：22

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