Organopalladium(IV) chemistry

被引：623

作者：

Xu, Ling-Min

Li, Bi-Jie

Yang, Zhen

Shi, Zhang-Jie ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 02期

关键词：

C-H ACTIVATION; ALKYLATION-ALKENYLATION REACTIONS; N BOND FORMATION; INTERMOLECULAR DIRECT ARYLATION; PALLADIUM-CATALYZED SYNTHESIS; BIDENTATE NITROGEN LIGANDS; CROSS-COUPLING REACTIONS; REDUCTIVE ELIMINATION; OXIDATIVE ADDITION; ARYL-ARYL;

D O I：

10.1039/b809912j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although the chemistry of Pd(0), Pd(I) and Pd(II) is well established, high oxidation state Pd(IV) complexes are less well-known. This situation has highly changed in recent years. Many well-defined Pd(IV) complexes has been isolated and characterized, providing evidence for a series of proposed Pd(II)/Pd(IV) catalytic reactions. A deep understanding of the behavior of Pd(IV) complexes could lead to the design and development of novel reactions that could not be accessed by traditional Pd(0)/Pd(II) chemistry. This critical review describes the stoichiometric reactions of Pd(IV) complexes and discusses their potential mechanism in catalytic reactions (137 references).

引用

收藏

页码：712 / 733

页数：22

相关论文

共 158 条

[21] Reactivity of diaryliodine(III) triflates toward palladium(II) and platinum(II):: Reactions of C(sp2)-I bonds to form arylmetal(IV) complexes;: Access to dialkyl(aryl)metal(IV), 1,4-benzenediyl-bridged platinum(IV), and triphenylplatinum(IV) species;: and structural studies of platinum(IV) complexes [J].

Canty, AJ ;

Patel, J ;

Rodemann, T ;

Ryan, JH ;

Skelton, BW ;

White, AH .

ORGANOMETALLICS, 2004, 23 (14) :3466-3473

[22] Oxidation of diorganopalladium(II) complexes by water and halogens: Reactions involving methyl group transfer and structural studies of hydrogen-bonded adducts formed by aryl alcohols with the pallada(IV)cyclopentane complex Pd(CH2CH2CH2CH2)(OH){(pz)(3)BH}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate) [J].

Canty, AJ ;

Jin, H ;

Roberts, AS ;

Skelton, BW ;

White, AH .

ORGANOMETALLICS, 1996, 15 (26) :5713-5722

[23] DEVELOPMENT OF ORGANOPALLADIUM(IV) CHEMISTRY - FUNDAMENTAL-ASPECTS AND SYSTEMS FOR STUDIES OF MECHANISM IN ORGANOMETALLIC CHEMISTRY AND CATALYSIS [J].

CANTY, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (02) :83-90

[24] Oxidation of complexes by (O2CPh)2 and (ER)2 (E = S, Se), including structures of Pd(CH2CH2CH2CH2)(SePh)2(bpy) (bpy = 2,2′-bipyridine) and MMe2(SePh)2(L2) (M = Pd, Pt; L2 = bpy, 1,10-phenanthroline) and C•••O and C•••E bond formation at palladium(IV) [J].

Canty, AJ ;

Jin, H ;

Skelton, BW ;

White, AH .

INORGANIC CHEMISTRY, 1998, 37 (16) :3975-3981

[25] Access to alkynylpalladium(IV) and -platinum(IV) species, including triorgano(diphosphine)metal(IV) complexes and the structural study of an alkynyl(pincer)platinum(IV) complex, Pt(O2CArF)I(CCSiMe3)(NCN) (ArF=4-CF3C6H4, NCN = [2,6-(dimethylaminomethyl)phenyl-N,C,N]-) [J].

Canty, Allan J. ;

Rodemann, Thomas ;

Skelton, Brian W. ;

White, Allan H. .

ORGANOMETALLICS, 2006, 25 (16) :3996-4001

[26] Intramolecular benzylic C-H activation: palladium-catalyzed synthesis of hexahydromethanofluorenes [J].

Catellani, M ;

Motti, E ;

Ghelli, S .

CHEMICAL COMMUNICATIONS, 2000, (20) :2003-2004

[27] Catalytic multistep reactions via palladacycles [J].

Catellani, M .

SYNLETT, 2003, (03) :298-313

[28] A novel palladium-catalyzed synthesis of phenanthrenes from ortho-substituted aryl iodides and diphenyl- or alkylphenylacetylenes [J].

Catellani, M ;

Motti, E ;

Baratta, S .

ORGANIC LETTERS, 2001, 3 (23) :3611-3614

[29] Selective aryl coupling via palladacycles: a new route to m-alkylbiphenyls or m-terphenyls [J].

Catellani, M ;

Motti, E .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (08) :759-761

[30] A complex catalytic cycle leading to a regioselective synthesis of o,o'-disubstituted vinylarenes [J].

Catellani, M ;

Frignani, F ;

Rangoni, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :119-122

← 1 2 3 4 5 6 7 8 9 10 →