Catalytic multistep reactions via palladacycles

被引：216

作者：

Catellani, M ^{[1
]}

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

来源：

SYNLETT | 2003年 / 03期

关键词：

multistep reactions; palladium(IV); palladacycle; deinsertion; C-H activation;

D O I：

10.1055/s-2003-37102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This account reports new methodologies to achieve multistep reactions under the catalytic action of palladium complexes. The metal control enables molecular pools consisting of several components to react in a definite order to form products with high chemo-, regio- and stereoselectivity. Key intermediates are palladacycles, which are formed and dismantled in the course of the reaction sequence.

引用

页码：298 / 313

页数：16

共 114 条

[1] PALLADIUM-CATALYZED DOMINO COUPLING REACTIONS OF ARYL HALIDES WITH NORBORNENE AND NORBORNENE DERIVATIVES - A SIMPLE ROUTE TO POLYCYCLIC AROMATIC-COMPOUNDS
ALBRECHT, K
REISER, O
WEBER, M
KNIERIEM, B
DEMEIJERE, A
[J]. TETRAHEDRON, 1994, 50 (02) : 383 - 401
[2] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
Amatore, C
Jutand, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
[3] AN ZW, 1990, GAZZ CHIM ITAL, V120, P383
[4] PALLADIUM-CATALYZED SYNTHESIS OF COUMARIN
AN, ZW
CATELLANI, M
CHIUSOLI, GP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) : C51 - C52
[5] PALLADIUM-CATALYZED PREPARATION OF EXO-ARYL DERIVATIVES OF THE NORBORNANE SKELETON
ARCADI, A
MARINELLI, F
BERNOCCHI, E
CACCHI, S
ORTAR, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (02) : 249 - 256
[6] REGIOSELECTIVITY CONTROL IN THE PALLADIUM-CATALYZED COPOLYMERIZATION OF PROPYLENE WITH CARBON-MONOXIDE
BATISTINI, A
CONSIGLIO, G
SUTER, UW
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (03): : 303 - 305
[7] Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy=2,2′-bipyridine)
Bayler, A
Canty, AJ
Ryan, JH
Skelton, BW
White, AH
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (11) : 575 - 578
[8] The heck reaction as a sharpening stone of palladium catalysis
Beletskaya, IP
Cheprakov, AV
[J]. CHEMICAL REVIEWS, 2000, 100 (08) : 3009 - 3066
[9] Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis
Bianchini, C
Meli, A
[J]. COORDINATION CHEMISTRY REVIEWS, 2002, 225 (1-2) : 35 - 66
[10] PALLADIUM-CATALYZED C-C BOND FORMATION INVOLVING AROMATIC C-H ACTIVATION .3. ASPECTS OF AROMATIC-SUBSTITUTION AND STRUCTURE OF 1-BROMO-3-[3-(2-METHYLENECYCLOHEX-5-EN-1-YL)BICYCLO[2.2.1]-HEPT-2-YL]-4-BICYCLO[2.2.1]HEPT-2-YLBENZENE
BOCELLI, G
CATELLANI, M
CHIUSOLI, GP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) : 225 - 232

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