Catalytic multistep reactions via palladacycles

被引：216

作者：

Catellani, M ^{[1
]}

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

来源：

SYNLETT | 2003年 / 03期

关键词：

multistep reactions; palladium(IV); palladacycle; deinsertion; C-H activation;

D O I：

10.1055/s-2003-37102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This account reports new methodologies to achieve multistep reactions under the catalytic action of palladium complexes. The metal control enables molecular pools consisting of several components to react in a definite order to form products with high chemo-, regio- and stereoselectivity. Key intermediates are palladacycles, which are formed and dismantled in the course of the reaction sequence.

引用

页码：298 / 313

页数：16

共 114 条

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