Formation of two-dimensional supramolecular water layer containing (H2O)18 morphology via dianion templating

被引：57

作者：

Luan, XJ

Chu, YC

Wang, YY ^{[1
]}

Li, DS

Liu, P

Shi, QZ

机构：

[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China

[2] NW Univ Xian, Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Peoples R China

[3] Yanan Univ, Dept Chem & Chem Engn, Yanan 716000, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 04期

关键词：

D O I：

10.1021/cg0504509

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fumaric sodium (Na(2)fum) reacts with CoCl2 center dot 6H(2)O to form a one-dimensional (ID) coordination polymeric structure {[Co(bpp)(2)(H2O)(2)]center dot fum-8H(2)O}(n) (1) in the presence of 1,3-bis(4-pyridyl)propane (bpp) from water at room temperature. An unprecedented two-dimensional (6,3) net topology of hydrogen-bonded water layers results from free water molecules through templating with fum. The I D polymeric chains behave as pillars to join these water sheets to make an overall three-dimensional supramolecular architecture by hydrogen-bonding interactions.

引用

页码：812 / 814

页数：3

共 43 条

[21] Quantum cluster equilibrium theory of liquids: Freezing of QCE/3-21G water to tetrakaidecahedral "Bucky-ice" [J].