A new carbonate bridged dinuclear zinc complex with tripodal amine ligands

被引：35

作者：

Dietrich, J ^{[1
]}

Heinemann, FW ^{[1
]}

Schrodt, A ^{[1
]}

Schindler, S ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany

来源：

INORGANICA CHIMICA ACTA | 1999年 / 288卷 / 02期

关键词：

crystal structures; zinc complexes; tripodal amine complexes; carbonate complexes;

D O I：

10.1016/S0020-1693(99)00093-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zinc complex with the tripodal ligand bis[2-(2-pyridyl)ethyl]-(2-pyridyl)methylamine (pmap) reacts with carbon dioxide to form a new dinuclear carbonate bridged zinc complex, [mu-CO3 {Zn(pmap)}(2)](ClO4)(2). This complex was structurally characterized and shows a binding mode for carbonate, which so far has not been observed for zinc carbonate complexes. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：206 / 209

页数：4

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