1,3-transposition of primary allylic alcohols: Synthesis of optically active secondary and tertiary allylic alcohols

被引：18

作者：

Dorta, RL

Rodriquez, MS

Salazar, JA

Suarez, E

机构：

[1] CSIC,INST PROD NAT & AGROBIOL,LA LAGUNA 38206,TENERIFE,SPAIN

[2] UNIV LA LAGUNA,DEPT QUIM ORGAN,E-38207 LA LAGUNA,TENERIFE,SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(97)00964-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of optically active 2,3-epoxy alcohols, suitably prepared by the Sharpless asymmetric epoxidation of primary allylic alcohols, with the system triphenylphosphine/iodine/imidazole/2,6-lutidine/water, leads in a single step to optically active secondary and tertiary allylic alcohols. (C) 1997 Elsevier Science Ltd.

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收藏

页码：4675 / 4678

页数：4

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