Compensation of radiation damping during selective pulses in NMR spectroscopy

被引:21
作者
Chen, JH
Jerschow, A
Bodenhausen, G [1 ]
机构
[1] Univ Lausanne, Chim Sect, BCH, CH-1015 Lausanne, Switzerland
[2] Ecole Normale Super, Dept Chim, CNRS, F-75231 Paris 05, France
关键词
D O I
10.1016/S0009-2614(99)00596-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A wide variety of amplitude- or phase-modulated pulses, which are designed for selective excitation, inversion or refocusing, are severely perturbed by radiation damping effects in the presence of a large macroscopic magnetisation. A general method is presented to compensate for radiation damping during the application of selective rf pulses. This method, which has general applicability for any amplitude- or frequency-modulated rf pulse, is demonstrated experimentally for inversion pulses. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:397 / 402
页数:6
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