Application of the dimenthyl chlorophosphite for the chiral analysis of amines, amino acids and peptides

被引:29
作者
Kolodiazhnyi, OI [1 ]
Demchuk, OM [1 ]
Gerschkovich, AA [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Bioorgan Chem, UA-253094 Kiev, Ukraine
关键词
D O I
10.1016/S0957-4166(99)00139-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title reagent for the determination of the enantiomeric excess of chiral amino acids and peptides was prepared from (-)-(1R,2S,5R)-menthol and PCl3. Its use as a chiral derivatizing agent for the determination of the enantiomeric content of amino acids and peptides by P-31 NMR is described. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1729 / 1732
页数:4
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