High-performance solution-processed triisopropylsilylethynyl pentacene transistors and inverters fabricated by using the selective self-organization technique

被引:32
作者
Kim, Se Hyun [1 ]
Choi, Danbi [1 ]
Chung, Dae Sung [1 ]
Yang, Chanwoo [1 ]
Jang, Jaeyoung [1 ]
Park, Chan Eon [1 ]
Park, Sang-Hee Ko [2 ]
机构
[1] Pohang Univ Sci & Technol, Dept Chem Engn, POSTECH Organ Elect Lab, Pohang 790784, South Korea
[2] Elect & Telecommun Res Inst, Transparent Elect Team, Taejon 305350, South Korea
关键词
D O I
10.1063/1.2987419
中图分类号
O59 [应用物理学];
学科分类号
摘要
To obtain selectively self-organized active layers of organic field-effect transistors (OFETs) and inverters from a solution-phased triisopropylsilylethynyl pentacene (TIPS-PEN) semiconductor, we locally patterned an oxide dielectric, covered with a hydrophobic fluoropolymer, using O-2 plasma etching. Drop-cast TIPS-PEN molecules were selectively crystallized on the O-2-plasma-etched area, where a hydrophilic oxide surface was produced. Modification of the patterned oxide dielectrics with hexamethyldisilazane led to a field-effect mobility of the TIPS-PEN OFETs of 0.185 cm(2) V-1 s(-1), a substhreshold swing of 0.738 V/decade and an on/off ratio of 10(7). Moreover, an inverter composed of two of these OFETs showed good device operation and inverter gain of 5.6. (c) 2008 American Institute of Physics.
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页数:3
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