Artificial molecular motors powered by light

被引:85
作者
Credi, A [1 ]
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
关键词
D O I
10.1071/CH06025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The bottom-up construction and operation of machines and motors of molecular size is a topic of great interest in nanoscience, and a fascinating challenge of nanotechnology. The problem of the energy supply to make molecular motors work is of the greatest importance. Research in the last ten years has demonstrated that light energy can indeed be used to power artificial nanomotors by exploiting photochemical processes in appropriately designed systems. More recently, it has become clear that under many aspects light is the best choice to power molecular motors; for example, systems that show autonomous operation and do not generate waste products can be obtained. This review is intended to discuss the design principles at the basis of light-driven artificial nanomotors, and provide an up-to-date overview on the prototype systems that have been developed.
引用
收藏
页码:157 / 169
页数:13
相关论文
共 112 条
[91]   DNA nanodevices [J].
Simmel, FC ;
Dittmer, WU .
SMALL, 2005, 1 (03) :284-299
[92]  
Stanier CA, 2002, ANGEW CHEM INT EDIT, V41, P1769, DOI 10.1002/1521-3773(20020517)41:10<1769::AID-ANIE1769>3.0.CO
[93]  
2-N
[94]   Light-driven production of ATP catalysed by F0F1-ATP synthase in an artificial photosynthetic membrane [J].
Steinberg-Yfrach, G ;
Rigaud, JL ;
Durantini, EN ;
Moore, AL ;
Gust, D ;
Moore, TA .
NATURE, 1998, 392 (6675) :479-482
[95]   Photoresponsive tweezers for alkali metal ions. Photochromic diarylethenes having two crown ether moieties [J].
Takeshita, M ;
Irie, M .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) :6643-6649
[96]   Light-driven molecular motors: Stepwise thermal helix inversion during unidirectional rotation of sterically overcrowded biphenanthrylidenes [J].
ter Wiel, MKJ ;
van Delden, RA ;
Meetsma, A ;
Feringa, BL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14208-14222
[97]   Control of rotor motion in a light-driven molecular motor: Towards a molecular gearbox [J].
ter Wiel, MKJ ;
van Delden, RA ;
Meetsma, A ;
Feringa, BL .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (22) :4071-4076
[98]   Epoxidation of polybutadiene by a topologically linked catalyst [J].
Thordarson, P ;
Bijsterveld, EJA ;
Rowan, AE ;
Nolte, RJM .
NATURE, 2003, 424 (6951) :915-918
[99]   Molecular gears: A pair of DNA circles continuously rolls against each other [J].
Tian, Y ;
Mao, CD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11410-11411
[100]   Molecular devices - A DNAzyme that walks processively and autonomously along a one-dimensional track [J].
Tian, Y ;
He, Y ;
Chen, Y ;
Yin, P ;
Mao, CD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4355-4358