Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

被引：168

作者：

Foo, Maw Lin ^{[1
,2
]}

Horike, Satoshi ^{[3
,4
]}

Fukushima, Tomohiro ^{[3
]}

Hijikata, Yuh ^{[3
]}

Kubota, Yoshiki ^{[5
]}

Takata, Masaki ^{[6
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Japan Sci & Technol Agcy, ERATO, Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[3] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[4] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[5] Osaka Prefecture Univ, Osaka, Japan

[6] Japan Synchrotron Radiat Res Inst SPring 8, Sayo, Hyogo 6795198, Japan

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 45期

关键词：

METAL-ORGANIC FRAMEWORKS; REDUCTION; CATALYSIS; NETS;

D O I：

10.1039/c2dt31195j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr6O4(OH)(4)(BDC-SO3H)(1.1)(BDC)(4.9) possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr6O4(OH)(4)(BDC)(6).

引用

收藏

页码：13791 / 13794

页数：4

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