Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups

被引：314

作者：

Akiyama, George ^{[1
]}

Matsuda, Ryotaro ^{[1
,2
,3
]}

Sato, Hiroshi ^{[1
,2
,3
]}

Takata, Masaki ^{[3
,4
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Japan Sci & Technol Agcy JST, Exploratory Res Adv Technol ERATO Kitagawa Integr, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Nishikyo Ku, Kyoto 6158510, Japan

[3] RIKEN SPring 8 Ctr, Mikazuki, Hyogo 6795148, Japan

[4] Japan Synchrotron Radiat Res Inst SPring 8, Mikazuki, Hyogo 6795148, Japan

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 29期

基金：

日本科学技术振兴机构;

关键词：

CONVERSION; GLUCOSE; WATER; CATALYSTS;

D O I：

10.1002/adma.201101356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A MIL-101-based porous coordination polymer (PCP) containing sulfonic acid groups is synthesized. The sulfonic groups are exposed on the pore surface and act as strong Bronsted acid sites. This solid acid PCP catalytically hydrolyzes cellulose into mono- and disaccharides and shows high durability in the catalytic reaction.

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页码：3294 / +

页数：5

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