Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

被引：264

作者：

Bernt, Stephan ^{[1
]}

Guillerm, Vincent ^{[2
]}

Serre, Christian ^{[2
]}

Stock, Norbert ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

[2] Univ Versailles St Quentin, Inst Lavoisier Versailles, CNRS, UMR 8180, Versailles, France

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

METAL-ORGANIC FRAMEWORKS; POROUS SOLIDS; STORAGE; FUNCTIONALIZATION; TOPOLOGY; MIL-101;

D O I：

10.1039/c0cc04526h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.

引用

收藏

页码：2838 / 2840

页数：3

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