Electroless polymerization of aniline on platinum and palladium surfaces

被引：42

作者：

Chen, YJ ^{[1
]}

Kang, ET ^{[1
]}

Neoh, KG ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem Engn, Singapore 119260, Singapore

来源：

APPLIED SURFACE SCIENCE | 2002年 / 185卷 / 3-4期

关键词：

platinum; palladium; polyaniline; polymerization; XPS; FTIR; AFM;

D O I：

10.1016/S0169-4332(01)00817-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aniline was found to polymerize slowly and spontaneously on the platinum and palladium metal surfaces in an aqueous acid solution of the monomer. The phenomenon was thus equivalent to an "electroless polymerization" process. The polyaniline (PANI) so-deposited were characterized by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, and atomic force microscopy (AFM). The chemical state of the electroless deposited PANI film was near to that of the 75% intrinsically oxidized nigraniline (NA) state of PANI. The electrolessly deposited PANI films exhibited similar protonation-deprotonation behavior as that of the aniline homopolymer. The amount of the PANI deposited on the metal surface was affected by the monomer concentration, the nature of the acid medium, and the oxygen content in the reaction medium. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：267 / 276

页数：10

共 42 条

[11] POLYANILINE - A HISTORICAL SURVEY [J].

GENIES, EM ;

BOYLE, A ;

LAPKOWSKI, M ;

TSINTAVIS, C .

SYNTHETIC METALS, 1990, 36 (02) :139-182

[12] ELECTROCHEMICAL STUDY OF POLYANILINE IN AQUEOUS AND ORGANIC MEDIUM - REDOX AND KINETIC-PROPERTIES [J].

GENIES, EM ;

SYED, AA ;

TSINTAVIS, C .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4) :181-186

[13]

GREEN AG, 1910, J CHEM SOC, P1117

[14] ANODIC DECOMPOSITION PATHWAYS OF ORTHO-SUBSTITUTED AND META-SUBSTITUTED ANILINES [J].

HAND, RL ;

NELSON, RF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (07) :1059-1069

[15]

HEEGER AJ, 1996, POLYM MAT ENCY SYNTH, P5500

[16] SURFACE CHARACTERISTICS OF THIN-FILMS PREPARED BY PLASMA AND ELECTROCHEMICAL POLYMERIZATIONS [J].

HERNANDEZ, R ;

DIAZ, AF ;

WALTMAN, R ;

BARGON, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (15) :3333-3337

[17] MODIFICATION OF THE CATALYTIC PROPERTIES OF SUPPORTED NOBLE-METAL CATALYSTS BY CARRIER DOPING [J].

IOANNIDES, T ;

VERYKIOS, XE .

CHEMICAL ENGINEERING & TECHNOLOGY, 1995, 18 (01) :25-32

[18] SIMULTANEOUS POLYMERIZATION AND FORMATION OF POLYACETYLENE FILM ON SURFACE OF CONCENTRATED SOLUBLE ZIEGLER-TYPE CATALYST SOLUTION [J].

ITO, T ;

SHIRAKAWA, H ;

IKEDA, S .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (01) :11-20

[19]

JOO J, 1993, INTRINSICALLY CONDUC, P165

[20]

KANG DP, 1989, SYNTHETIC MET, V29, pE343

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