Ti(OiPr)4-mediated nudeophilic substitution of propargylic esters

被引：26

作者：

Mahrwald, R ^{[1
]}

Quint, S ^{[1
]}

Scholtis, S ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

TETRAHEDRON | 2002年 / 58卷 / 49期

关键词：

propargylic esters; nucleophilic substitution; ethers; titanium complexes;

D O I：

10.1016/S0040-4020(02)01286-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct and catalytic displacement reactions of propargylic esters are reported. The reaction is based on the Ti(OR)(4)/alpha-hydroxy acid mediated ligand exchange. This methodology enables the inclusion of a broad range of acetylenes and aldehydes into this substitution reaction. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：9847 / 9851

页数：5

共 24 条

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Yang, FL
Zhao, G
Ding, Y
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