N-cyclopropylimine-1-pyrroline rearrangement.: A novel photochemical reaction

被引:47
作者
Campos, PJ [1 ]
Soldevilla, A [1 ]
Sampedro, D [1 ]
Rodríguez, MA [1 ]
机构
[1] Univ La Rioja, Dept Quim, Grp Sintesis Quim La Rioja, CSIC,Unidad Asociada, E-26006 Logrono, Spain
关键词
D O I
10.1021/ol016847x
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] A novel aza-(vinylcyclopropane-cyclopentene) photochemical rearrangement is reported. 1-Pyrrolines are easily synthesized in good yields from N-cyclopropylimines. Hydrogen, alkyl, and aryl groups can be placed anywhere within the system, and the reaction proceeds regiospecifically.
引用
收藏
页码:4087 / 4089
页数:3
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