N-heterocyclic carbenes in gold catalysis

被引:666
作者
Marion, Nicolas [1 ]
Nolan, Steven P. [1 ]
机构
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
关键词
D O I
10.1039/b711132k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The appealing properties of N-heterocyclic carbenes (NHC) as ancillary ligands and the high potential of gold as an organometallic catalyst have made their encounter inevitable. Still in its infancy, NHC-gold catalysis is nevertheless growing rapidly. In this tutorial review, catalytic transformations involving NHC-containing gold(I) and gold(III) complexes are presented. Particular attention is drawn to the versatility and selectivity of these catalysts.
引用
收藏
页码:1776 / 1782
页数:7
相关论文
共 42 条
[41]   Gold-promoted styrene polymerization [J].
Urbano, Juan ;
Hormigo, A. Jesus ;
de Fremont, Pierre ;
Nolan, Steven P. ;
Diaz-Requejo, M. Mar ;
Perez, Pedro J. .
CHEMICAL COMMUNICATIONS, 2008, (06) :759-761
[42]   Gold(I)-catalyzed oxidative rearrangements [J].
Witham, Cole A. ;
Mauleon, Pablo ;
Shapiro, Nathan D. ;
Sherry, Benjamin D. ;
Toste, F. Dean .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (18) :5838-+