Synthesis, crystal structure and luminescent properties of a thiocyanato bridged two-dimensional heteronuclear polymeric complex of cadmium(II) and copper(II)

被引：42

作者：

Bai, Yan ^{[1
]}

Shang, Wei-Li ^{[1
]}

Dang, Dong-Bin ^{[1
]}

Gao, Hui ^{[1
]}

Niu, Xiao-Fang ^{[1
]}

Guan, Yang-Fan ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Heteronuclear complex; Thiocyanato bridged; Crystal structure; Luminescent properties;

D O I：

10.1016/j.inoche.2008.10.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel heteronuclear polymeric complex Cd(SCN)(3)Cu(en)(2)NO3 (1) (en = ethylenedia mine) has been synthesized and structurally characterized. The Cd(II) atom is surrounded by three S atoms and three N atoms from four 1,3-mu-SCN- and two 1,1,3-mu-SCN- to attain a distorted octahedral coordination geometry. Six Cd(II) centers are linked by twelve thiocyanato bridges to form hexagonal metallocyclic unit [Cd-6(SCN)(12)] and extend a 2D network. Moreover, a 1,1,3-mu-SCN- links two cadmium and one copper metal atoms. The luminescent properties of 1 in the solid state were investigated. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1470 / 1473

页数：4

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