Combined Characterization Techniques to Understand the Stability of a Variety of Organic Photovoltaic Devices - the ISOS-3 inter-laboratory collaboration

被引：2

作者：

Lira-Cantu, Monica ^{[1
]}

Tanenbaum, David M. ^{[2
,3
]}

Norrman, Kion ^{[2
,6
]}

Voroshazi, Eszter ^{[4
,5
]}

Hermenau, Martin ^{[3
]}

Lloyd, Matthew T. ^{[7
]}

Teran-Escobar, Gerardo ^{[1
]}

Galagan, Yulia ^{[8
]}

Zimmermann, Birger ^{[9
]}

Hosel, Markus ^{[2
]}

Dam, Henrik F. ^{[2
]}

Jorgensen, Mikkel ^{[2
]}

Gevorgyan, Suren ^{[2
]}

Lutsen, Laurence ^{[10
]}

Vanderzande, Dirk ^{[11
]}

Hoppe, Harald ^{[12
]}

Roesch, Roland ^{[12
]}

Wuerfel, Uli

Andriessen, Ronn ^{[8
]}

Rivaton, Agnes ^{[15
,16
]}

Uzunoglu, Gulsah Y. ^{[13
]}

Germack, David ^{[14
]}

Andreasen, Birgitta ^{[2
]}

Madsen, Morten V. ^{[2
]}

Bundgaard, Eva ^{[2
]}

Krebs, Frederik C. ^{[2
]}

机构：

[1] ETSE, Ctr Invest Nanociencia & Nanotecnol CIN2, CSIC, Lab Nanostruct Mat Photovolta Energy, Campus UAB,Edifici Q,2nd Floor, Barcelona, Spain

[2] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark

[3] Pomona Coll, Dept Phys & Astron, Claremont, CA 91711 USA

[4] IMEC, B-3000 Louvain, Belgium

[5] Katholieke Univ Leuven, B-3000 Louvain, Belgium

[6] Tech Univ Dresden, Inst Angew Photophys, Arbeitsgrp Organ Solarzellen OSOL, D-01062 Dresden, Germany

[7] Natl Renewable Energy Lab, Golden, CO 80401 USA

[8] Holst Ctr, NL-5656 Eindhoven, Netherlands

[9] Fraunhofer Inst Solar Energy Syst ISE, D-79110 Freiburg, Germany

[10] IMEC, IMOMEC Assoc Lab, B-3590 Diepenbeek, Belgium

[11] Hasselt Univ, E-08193 Barcelona, Spain

[12] Tech Univ Ilmenau, Inst Phys, G-98693 Ilmenau, Germany

[13] TUBITAK Natl Metrol Inst UME, TR-41470 Gebze, Kocaeli, Turkey

[14] Brookhaven Natl Lab, Condensed Matter Phys, Upton, NY 11973 USA

[15] Clermont Univ, Univ Blaise Pascal, LPMM, Clermont Ferrand, France

[16] CNRS, UMR6505, LPMM, F-63177 Clermont Ferrand, France

来源：

RELIABILITY OF PHOTOVOLTAIC CELLS, MODULES, COMPONENTS, AND SYSTEMS V | 2012年 / 8472卷

关键词：

Polymer solar cells; organic solar cells; stability; metal electrodes; polymer/metal interaction; degradation; POLY(3-HEXYLTHIOPHENE) P3HT; POLYTHIOPHENES; METALLIZATION;

D O I：

10.1117/12.929579

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

This work is part of the inter-laboratory collaboration to study the stability of seven distinct sets of state-of-the-art organic photovoltaic (OPVs) devices prepared by leading research laboratories. All devices have been shipped to and degraded at the Danish Technical University (DTU, formerly RISO-DTU) up to 1830 hours in accordance with established ISOS-3 protocols under defined illumination conditions. In this work we present a summary of the degradation response observed for the NREL sample, an inverted OPV of the type ITO/ZnO/P3HT:PCBM/PEDOT:PSS/Ag/Al, under full sun stability test. The results reported from the combination of the different characterization techniques results in a proposed degradation mechanism. The final conclusion is that the failure of the photovoltaic response of the device with time under full sun solar simulation, is mainly due to the degradation of the electrodes and not to the active materials of the solar cell.

引用

页数：6

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