Unexpected polymeric string formation between Ag(I) and a homoleptic thioether cage:: synthesis and crystal structure of [R,R′-S6tricosane] and {[Ag(R,R′-S6hexacosane)]TsO}∞

被引：21

作者：

Alberto, R ^{[1
]}

Angst, D

Abram, U

Ortner, K

Kaden, TA

Schubiger, AP

机构：

[1] Paul Scherrer Inst, Ctr Radiopharm, CH-5232 Villigen, Switzerland

[2] Forschungszentrum Rossendorf EV, Inst Radiochem, D-01062 Dresden, Germany

[3] Univ Basel, Dept Inorgan Chem, CH-5067 Basel, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a903455b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The large cavity homoleptic thioether cages [R,R'-S(6)tricosane] (1-hydroxymethyl-9-methyl-3,7,11,15,18,22-hexathiabicyclo[7.7.7]tricosane) (1) and [R,R'-S(6)hexacosane] (1-hydroxymethyl-10-methyl-3,8,12,17,20,25-hexathiabicyclo-[8.8.8]hexacosane) (2) have been synthesized and the structures of 1 and of the complex {[Ag(2)]TsO}(infinity) have been elucidated, the latter showing a polymeric string structure with Ag+ coordinated by three different cages.

引用

页码：1513 / 1514

页数：2

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