MAPLE deposition of biomaterial multilayers

被引：26

作者：

Califano, Valeria ^{[1
]}

Bloisi, Francesco ^{[1
,2
]}

Vicari, Luciano R. M. ^{[1
,2
]}

Colombi, Paolo ^{[3
]}

Bontempi, Elza ^{[3
]}

Depero, Laura E. ^{[3
]}

机构：

[1] Univ Naples Federico 2, CNR, INFM Coherentia, I-80125 Naples, Italy

[2] Univ Naples Federico 2, Dipartimento Sci Fisiche, Fac Ingn, I-80125 Naples, Italy

[3] Univ Brescia, Lab Chim Tecnol, I-25123 Brescia, Italy

来源：

APPLIED SURFACE SCIENCE | 2008年 / 254卷 / 22期

关键词：

MAPLE; surface morphology; thin films; polyethylene glycol;

D O I：

10.1016/j.apsusc.2008.05.295

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Double layers of polyethylene glycol (PEG) and 3-(3,4-dihydroxyphenyl)-2-methyl-L-alanine (m-DOPA) thin films were obtained by matrix assisted pulsed laser evaporation (MAPLE) technique, by depositing a first layer of m-DOPA on Si substrate and a second layer of PEG on top of it. The films were characterized by low angle X-ray diffraction (LAXRD), X-ray reflectivity (XRR), atomic force microscopy (AFM), and micro-Raman spectroscopy. From these analyses it resulted that PEG was deposited without any relevant damage both in terms of chemical structure and molecular weight. Furthermore, PEG chains were mostly in the extended conformation, although PEG micelles appeared. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：7143 / 7148

页数：6

共 39 条

[21] Monitoring of glass derivatization with pulsed force mode atomic force microscopy [J].

Ebner, A ;

Kienberger, F ;

Stroh, CM ;

Gruber, HJ ;

Hinterdorfer, P .

MICROSCOPY RESEARCH AND TECHNIQUE, 2004, 65 (4-5) :246-251

[22]

Golander C-G., 1992, POLYETHYLENE GLYCOL, P221, DOI DOI 10.1007/978-1-4899-0703-5_15.

[23] Water partitioning in "dry" poly(ethylene oxide) alcohol (Cm En) nonionic surfactant -: a proton NMR study [J].

Hoffmann, MM ;

Bennett, ME ;

Fox, JD ;

Wyman, DP .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 287 (02) :712-716

[24] Matrix-assisted pulsed laser evaporation of polymeric materials: a molecular dynamics study [J].

Itina, TE ;

Zhigilei, LV ;

Garrison, BJ .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2001, 180 :238-244

[25] Electrical response characterisation of poly(ethylene glycol) macromer (PEGM)/chitosan hydrogels in NaCl solution [J].

Kaewpirom, Supranee ;

Boonsang, Siridech .

EUROPEAN POLYMER JOURNAL, 2006, 42 (07) :1609-1616

[26] Molecular dynamics simulation study of the ejection and transport of polymer molecules in matrix-assisted pulsed laser evaporation [J].

Leveugle, Elodie ;

Zhigilei, Leonid V. .

JOURNAL OF APPLIED PHYSICS, 2007, 102 (07)

[27] Chemical and spectroscopic aspects of polymer ablation: Special features and novel directions [J].

Lippert, T ;

Dickinson, JT .

CHEMICAL REVIEWS, 2003, 103 (02) :453-485

[28] Synthesis of novel thin-film materials by pulsed laser deposition [J].

Lowndes, DH ;

Geohegan, DB ;

Puretzky, AA ;

Norton, DP ;

Rouleau, CM .

SCIENCE, 1996, 273 (5277) :898-903

[29] Influence of polymer molecular weight on the solid-state structure of PEG/monoolein mixtures [J].

Mahlin, D ;

Unga, J ;

Ridell, A ;

Frenning, G ;

Engström, S .

POLYMER, 2005, 46 (26) :12210-12217

[30] Characterization of ultrathin poly(ethylene glycol) monolayers on silicon substrates [J].

Papra, A ;

Gadegaard, N ;

Larsen, NB .

LANGMUIR, 2001, 17 (05) :1457-1460

← 1 2 3 4 →