Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

被引：300

作者：

Ackermann, Lutz ^{[1
]}

Althammer, Andreas ^{[1
]}

Fenner, Sabine ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 01期

关键词：

C-H activation; direct arylation; heteroarenes; palladium; sulfonates; CROSS-COUPLING REACTIONS; H BOND ACTIVATION; C-H; ARYL CHLORIDES; HALOGENATED NITROGEN; FUNCTIONALIZATION; HETEROCYCLES; OXYGEN; 1,2,3-TRIAZOLES; PRELIGANDS;

D O I：

10.1002/anie.200804517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A toss up: A highly active palladium complex enabled the first direct arylation of heteroarenes through C-H bond functionalization using tosylates or mesylates as electrophiles with ample scope. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：201 / 204

页数：4

共 58 条

[1] Catalytic arylation reactions by C-H bond activation with aryl tosylates
Ackermann, L
Althammer, A
Born, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (16) : 2619 - 2622
[2] Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate
Ackermann, L
Gschrei, CJ
Althammer, A
Riederer, M
[J]. CHEMICAL COMMUNICATIONS, 2006, (13) : 1419 - 1421
[3] Phosphine oxides as preligands in ruthenium-catalyzed arylations via C-H bond functionalization using aryl chlorides
Ackermann, L
[J]. ORGANIC LETTERS, 2005, 7 (14) : 3123 - 3125
[4] Ackermann L., 2007, ANGEW CHEM, V119, P6482
[5] Ackermann L., 2006, Angew. Chem, V118, P7789
[6] Copper-catalyzed "click" reaction/direct arylation sequence: Modular syntheses of 1,2,3-triazoles
Ackermann, Lutz
Potukuchi, Harish K.
Landsberg, Dirk
Vicente, Ruben
[J]. ORGANIC LETTERS, 2008, 10 (14) : 3081 - 3084
[7] Assisted ruthenium-catalyzed C-H bond activation: Carboxylic acids as cocatalysts for generally applicable direct arylations in apolar solvents
Ackermann, Lutz
Vicente, Ruben
Althammer, Andreas
[J]. ORGANIC LETTERS, 2008, 10 (11) : 2299 - 2302
[8] Palladium-catalyzed direct arylations of 1,2,3-triazoles with aryl chlorides using conventional heating
Ackermann, Lutz
Vicente, Ruben
Born, Robert
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (05) : 741 - 748
[9] Ackermann L, 2007, TOP ORGANOMETAL CHEM, V24, P35, DOI 10.1007/3418_2007_062
[10] [RuCl3(H2O)n]-catalyzed direct arylations with bromides as electrophiles
Ackermann, Lutz
Althammer, Andreas
Born, Robert
[J]. SYNLETT, 2007, (18) : 2833 - 2836

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