Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

被引：300

作者：

Ackermann, Lutz ^{[1
]}

Althammer, Andreas ^{[1
]}

Fenner, Sabine ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 01期

关键词：

C-H activation; direct arylation; heteroarenes; palladium; sulfonates; CROSS-COUPLING REACTIONS; H BOND ACTIVATION; C-H; ARYL CHLORIDES; HALOGENATED NITROGEN; FUNCTIONALIZATION; HETEROCYCLES; OXYGEN; 1,2,3-TRIAZOLES; PRELIGANDS;

D O I：

10.1002/anie.200804517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A toss up: A highly active palladium complex enabled the first direct arylation of heteroarenes through C-H bond functionalization using tosylates or mesylates as electrophiles with ample scope. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：201 / 204

页数：4

共 58 条

[51] So C. M., 2008, ANGEW CHEM, V120, P8179, DOI DOI 10.1002/ANGE.200803193
[52] A General Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Mesylates
So, Chau Ming
Lau, Chak Po
Kwong, Fuk Yee
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (42) : 8059 - 8063
[53] ATOM ECONOMY - A CHALLENGE FOR ORGANIC-SYNTHESIS - HOMOGENEOUS CATALYSIS LEADS THE WAY
TROST, BM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (03) : 259 - 281
[54] Tsuji J., 2004, PALLADIUM REAGENTS C, DOI DOI 10.1002/0470021209.CH1
[55] σ-Chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts:: regioselectivity, stereoselectivity and catalytic turnover
Yu, Jin-Quan
Giri, Ramesh
Chen, Xiao
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (22) : 4041 - 4047
[56] Synthesis of heterocycles via palladium-catalyzed oxidative addition
Zeni, Gilson
Larock, Richard C.
[J]. CHEMICAL REVIEWS, 2006, 106 (11) : 4644 - 4680
[57] Palladium-catalyzed Hiyama cross-couplings of aryl arenesulfonates with arylsilanes
Zhang, Liang
Wu, Jie
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) : 12250 - +
[58] Palladium-catalyzed Negishi cross-coupling reactions of unactivated alkyl iodides, bromides, chlorides, and tosylates
Zhou, JR
Fu, GC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (41) : 12527 - 12530

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