Thioesters synthesis: recent adventures in the esterification of thiols

被引：126

作者：

Kazemi, Mosstafa ^{[1
]}

Shiri, Lotfi ^{[1
]}

机构：

[1] Ilam Univ, Fac Basic Sci, Dept Chem, Ilam, Iran

来源：

JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 06期

关键词：

thioester; organosulfur compounds; esterification; acylation; thiol; pharmaceutical; synthesis; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; HIGHLY EFFICIENT; IONIC LIQUIDS; CATALYZED ACYLATION; ROOM-TEMPERATURE; CARBOXYLIC-ACIDS; HETEROGENEOUS CATALYST; GRIGNARD-REAGENTS; CONVENIENT METHOD;

D O I：

10.1080/17415993.2015.1075023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thioesters are important class of organosulfur compounds that play a fundamental role in the construction of pharmaceutical, biological, industrial and natural products. In this respect, thioesters synthesis is one of the most important tasks in organosulfur chemistry. The esterification of thiols is the best and most common strategy for the synthesis of thioesters. During the last decade (from 2005 to 2015), the application of a diverse range of reagents as activating or promoter agents for the acylation of thiols in order to synthesize thioesters have been investigated by various research teams. In this review, we have summarized and studied recently reported synthetic protocols in the arena of acylation of thiols. [GRAPHICS] .

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页码：613 / 623

页数：11

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