Formation of pseudorotaxane induced by electrochemical oxidation of ferrocene-containing axis molecule in the presence of crown ether

被引：57

作者：

Horie, M ^{[1
]}

Suzaki, Y ^{[1
]}

Osakada, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期

关键词：

D O I：

10.1021/ja039899l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical oxidation of aminomethylferrocenes in the presence of dibenzo[24]crown-8 affords pseudorotaxanes containing a ferrocenyl group in its axis moiety. The formation of the pseudorotaxanes results from formation of secondary ammonium ions by rapid electron transfer from the N atom to the initially formed Fe(III) state, followed by hydrogen atom transfer from TEMPOH to the N+•. Copyright © 2004 American Chemical Society.

引用

页码：3684 / 3685

页数：2

共 28 条

[1] Electrochemically switchable hydrogen-bonded molecular shuttles
Altieri, A
Gatti, FG
Kay, ER
Leigh, DA
Martel, D
Paolucci, F
Slawin, AMZ
Wong, JKY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) : 8644 - 8654
[2] Redox potential selection in a new class of dendrimers containing multiple ferrocene centers
Alvarez, J
Ren, T
Kaifer, AE
[J]. ORGANOMETALLICS, 2001, 20 (16) : 3543 - 3549
[3] Structural and pH control on the electronic communication between two identical ferrocene sites
Alvarez, J
Kaifer, AE
[J]. ORGANOMETALLICS, 1999, 18 (26) : 5733 - 5734
[4] Synthesis of a water-soluble conjugated [3]rotaxane
Anderson, S
Anderson, HL
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (17): : 1956 - 1959
[5] An approach to insulated molecular wires: synthesis of water-soluble conjugated rotaxanes
Anderson, S
Aplin, RT
Claridge, TDW
Goodson, T
Maciel, AC
Rumbles, G
Ryan, JF
Anderson, HL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (15): : 2383 - 2397
[6] A MOLECULAR SHUTTLE
ANELLI, PL
SPENCER, N
STODDART, JF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5131 - 5133
[7] Acid-base controllable molecular shuttles
Ashton, PR
Ballardini, R
Balzani, V
Baxter, I
Credi, A
Fyfe, MCT
Gandolfi, MT
Gómez-López, M
Martínez-Díaz, MV
Piersanti, A
Spencer, N
Stoddart, JF
Venturi, M
White, AJP
Williams, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) : 11932 - 11942
[8] Controlling multivalent interactions in triply-threaded two-component superbundles
Balzani, V
Clemente-León, M
Credi, A
Lowe, JN
Badjic, JD
Stoddart, JF
Williams, DJ
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (21) : 5348 - 5360
[9] Molecular machines
Balzani, V
Gómez-López, M
Stoddart, JF
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) : 405 - 414
[10] Switching of pseudorotaxanes and catenanes incorporating a tetrathiafulvalene unit by redox and chemical inputs
Balzani, V
Credi, A
Mattersteig, G
Matthews, OA
Raymo, FM
Stoddart, JF
Venturi, M
White, AJP
Williams, DJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (07) : 1924 - 1936

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