Formation of pseudorotaxane induced by electrochemical oxidation of ferrocene-containing axis molecule in the presence of crown ether

被引：57

作者：

Horie, M ^{[1
]}

Suzaki, Y ^{[1
]}

Osakada, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期

关键词：

D O I：

10.1021/ja039899l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical oxidation of aminomethylferrocenes in the presence of dibenzo[24]crown-8 affords pseudorotaxanes containing a ferrocenyl group in its axis moiety. The formation of the pseudorotaxanes results from formation of secondary ammonium ions by rapid electron transfer from the N atom to the initially formed Fe(III) state, followed by hydrogen atom transfer from TEMPOH to the N+•. Copyright © 2004 American Chemical Society.

引用

页码：3684 / 3685

页数：2

共 28 条

[11] A CHEMICALLY AND ELECTROCHEMICALLY SWITCHABLE MOLECULAR SHUTTLE
BISSELL, RA
CORDOVA, E
KAIFER, AE
STODDART, JF
[J]. NATURE, 1994, 369 (6476) : 133 - 137
[12] Information storage using supramolecular surface patterns
Cavallini, M
Biscarini, F
Léon, S
Zerbetto, F
Bottari, G
Leigh, DA
[J]. SCIENCE, 2003, 299 (5606) : 531 - 531
[13] Supramolecular pseudorotaxane polymers from complementary pairs of homoditopic molecules
Gibson, HW
Yamaguchi, N
Jones, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) : 3522 - 3533
[14] Cyclodextrin-based molecular machines
Harada, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) : 456 - 464
[15] THE MOLECULAR NECKLACE - A ROTAXANE CONTAINING MANY THREADED ALPHA-CYCLODEXTRINS
HARADA, A
LI, J
KAMACHI, M
[J]. NATURE, 1992, 356 (6367) : 325 - 327
[16] A new azaferrocenophane with an azobenzene-containing ligand. Remote control of photoisomerization of the azobenzene group by redox of the iron center
Horie, M
Sakano, T
Osakada, K
Nakao, H
[J]. ORGANOMETALLICS, 2004, 23 (01) : 18 - 20
[17] Template routes to interlocked molecular structures and orderly molecular entanglements
Hubin, TJ
Busch, DH
[J]. COORDINATION CHEMISTRY REVIEWS, 2000, 200 : 5 - 52
[18] A cyclodextrin-based molecular shuttle containing energetically favored and disfavored portions in its dumbbell component
Kawaguchi, Y
Harada, A
[J]. ORGANIC LETTERS, 2000, 2 (10) : 1353 - 1356
[19] NEWER ASPECTS OF SYNTHESIS AND CHEMISTRY OF NITROXIDE SPIN LABELS
KEANA, JFW
[J]. CHEMICAL REVIEWS, 1978, 78 (01) : 37 - 64
[20] Spectroelectrochemical characterization of Si-bridged diphenylamines: Influence of Si-bridging upon electronic structures of diphenylamines
Nakao, H
Hayashi, H
Okita, K
[J]. ANALYTICAL SCIENCES, 2001, 17 (04) : 545 - 549

← 1 2 3 →