Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction

被引：124

作者：

Bunzen, Jens ^{[1
]}

Iwasa, Junji ^{[2
]}

Bonakdarzadeh, Pia ^{[1
]}

Numata, Eri ^{[2
]}

Rissanen, Kari ^{[1
]}

Sato, Sota ^{[2
]}

Fujita, Makoto ^{[2
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, NanoSci Ctr, Jyvaskyla 40014, Finland

[2] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 13期

基金：

芬兰科学院;

关键词：

palladium; pyrroles; self-assembly; spherical structures; COORDINATION CAGES; TOPOLOGY; SPHERES;

D O I：

10.1002/anie.201108731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M 12L 24 or M 24L 48). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M 12L 24/M 24L 48 switchover. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3161 / 3163

页数：3

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