Compatibility of lithium salts with solvent of the non-aqueous electrolyte in Li-O2 batteries

被引：62

作者：

Du, Peng ^{[1
]}

Lu, Jun ^{[1
]}

Lau, Kah Chun ^{[2
]}

Luo, Xiangyi ^{[1
,3
]}

Bareno, Javier ^{[1
]}

Zhang, Xiaoyi ^{[4
]}

Ren, Yang ^{[4
]}

Zhang, Zhengcheng ^{[1
]}

Curtiss, Larry A. ^{[2
]}

Sun, Yang-Kook ^{[5
,6
]}

Amine, Khalil ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Lemont, IL 60439 USA

[3] Univ Utah, Dept Met Engn, Salt Lake City, UT 84112 USA

[4] Argonne Natl Lab, Xray Sci Div, Adv Photon Source, Lemont, IL 60439 USA

[5] Hanyang Univ, Dept WCU Energy Engn, Seoul 133791, South Korea

[6] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 15期

关键词：

AIR BATTERIES; POLYMER ELECTROLYTE; NANOWIRES; STABILITY; CHEMISTRY;

D O I：

10.1039/c3cp50500f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stability of lithium salts, especially in the presence of reduced oxygen species, O-2 and H2O (even in a small amount), plays an important role in the cyclability and capacity of Li-O-2 cells. This combined experimental and computational study provides evidence that the stability of the electrolyte used in Li-O-2 cells strongly depends on the compatibility of lithium salts with solvent. In the case of the LiPF6-1NM(3) electrolyte, the decomposition of LiPF6 occurs in the cell as evidenced by in situ XRD, FT-IR and XPS analysis, which triggers the decomposition of 1NM3 solvent due to formation of HF from the decomposition of LiPF6. These reactions lead to degradation of the electrolyte and cause poor cyclability of the cell. The same reactions are not observed when LiTFSI and LiCF3SO3 are used as the lithium salts in 1NM3 solvent, or LiPF6 is used in TEGDME solvent.

引用

页码：5572 / 5581

页数：10

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