Cellulose Nanowhisker-incorporated Poly(Lactic Acid) Composites for High Thermal Stability

被引:23
作者
Cho, Se Youn [1 ]
Park, Hyun Ho [1 ]
Yun, Young Soo [1 ]
Jin, Hyoung-Joon [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402571, South Korea
关键词
Cellulose nanocrystals; Poly(lactic acid); Composites; MICROCRYSTALLINE CELLULOSE; HYDROLYSIS; WHISKERS;
D O I
10.1007/s12221-013-1001-y
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
082103 [纺织化学与染整工程]; 082905 [生物质能源与材料];
摘要
In this study, biodegradable composites were prepared using cellulose nanowhiskers and poly(lactic acid). For processing at high temperature over 200 degrees C, cellulose nanowhiskers were prepared by ultra-sound treatment, with the high thermal stability of natural cellulose. The nanowhiskers were confirmed using transmission electron microscopy, X-ray diffraction, and thermo-gravimetric analysis. Surface modification of the cellulose nanowhiskers was performed to increase the adhesion between hydrophilic nanofillers and hydrophobic polymer matrix. The dynamic mechanical thermal analysis of the composites showed better reinforcing effect of the modified cellulose nanocrystals. The effects of cellulose nanowhiskers on the biodegradability of poly(lactic acid) were studied using a microbial oxidative degradation analyzer.
引用
收藏
页码:1001 / 1005
页数:5
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