Traceless Chiral Auxiliaries for the Allene Ether Nazarov Cyclization

被引：55

作者：

Banaag, April R.

Tius, Marcus A. ^{[1
]}

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 21期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1021/jo801503c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The key stereochemical factors that determine transfer of asymmetry from the chiral auxiliary to the cyclopentenone in the allene ether version of the Nazarov reaction have been elucidated. On the basis of the new insights into the mechanism, two highly effective chiral auxiliaries were designed and prepared.

引用

页码：8133 / 8141

页数：9

共 52 条

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