Design of chiral auxiliaries for the allene ether Nazarov cyclization

被引：40

作者：

Banaag, April R.

Tius, Marcus A.

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

[2] Canc Res Ctr Hawaii, Honolulu, HI 96813 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 17期

关键词：

D O I：

10.1021/ja069342g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 1,3- or a 1,4-cis axial tert-butyldimethylsilyloxy substituent on the pyranose derived chiral auxiliary for the allene ether Nazarov cyclization leads to products in high optical purity. alpha-Pyranose and beta-pyranose derived auxiliaries lead to enantiomeric products.

引用

页码：5328 / +

页数：3

共 17 条

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