Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries

被引：1034

作者：

Masquelier, Christian ^{[1
,3
,4
]}

Croguennec, Laurence ^{[2
,3
,4
]}

机构：

[1] Univ Picardie Jules Vemes, UMR CNRS 7314, Lab React & Chim Solides, F-80039 Amiens 1, France

[2] Univ Bordeaux, CNRS, ICMCB, UPR 9048, F-33600 Pessac, France

[3] FR CNRS 3104, ALISTORE ERI, F-80039 Amiens 1, France

[4] FR CNRS 3459, Reseau Stockage Electrochim Energie RS2E, Paris, France

来源：

CHEMICAL REVIEWS | 2013年 / 113卷 / 08期

关键词：

LITHIUM VANADIUM FLUOROPHOSPHATE; ELECTROCHEMICAL INSERTION PROPERTIES; LIFEPO4 SYNTHESIS ROUTES; SOLID-SOLUTION PHASES; X-RAY-DIFFRACTION; CATHODE MATERIAL; CRYSTAL-STRUCTURE; POSITIVE-ELECTRODE; MAGNETIC-PROPERTIES; IRON-PHOSPHATE;

D O I：

10.1021/cr3001862

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The concept of investigating three-dimensional frameworks based on the NASICON structure as hosts for reversible insertion/extraction of alkali cations (electrodes) arose in the mid 1980s mostly from concerns about possible stability or reactivity versus metallic Na (or Li) when used as solid electrolytes. The NASICON framework was used by Goodenough in the late 1980s as a very demonstrative example of the possibility for the chemist to elaborate electrode materials functioning at controlled operating voltages. Noticeably, these structures have been recently investigated by three independent groups as model compounds for the understanding of complex Li NMR signals in paramagnetic compounds, and useful insights into the activation energies for hopping between the lithium sites were provided.

引用

页码：6552 / 6591

页数：40

共 463 条

[81] Analysis of the uniaxial magnetic properties of high-spin d6 ions at trigonal prism and linear two-coordinate sites:: Uniaxial magnetic properties of Ca3Co2O6 and Fe[C(SiMe3)3]2 [J].