Reversible, Metal-Free, Heterolytic Activation of H2 at Room Temperature

被引：206

作者：

Ullrich, Matthias ^{[1
]}

Lough, Alan J. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

AMINE-BORANE ADDUCTS; BORON-NITROGEN BONDS; AMMONIA-BORANE; CATALYZED DEHYDROGENATION; DIHYDROGEN ACTIVATION; MOLECULAR-STRUCTURE; LEWIS ACIDITY; HYDROGEN; AMINOBORANES; COMPLEXES;

D O I：

10.1021/ja808506t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

B(p-C6F4H)(3) + P(o-C6H4Me)(3) 25 degrees C, vacuum up down arrow 25 degrees C, H-2 [HB(p-C6F4H)(3)][HP(o-C6H4Me)(3)] The combination of the borane B(p-C6F4H)(3) and (o-C6H4Me)(3)P activates H-2 to give [(o-C6H4Me)(3)PH][HB(P-C6F4H)(3)]. This salt when placed under vacuum releases H-2 at room temperature.

引用

页码：52 / +

页数：3

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