Facile heterolytic H2 activation by amines and B(C6F5)3

被引：317

作者：

Sumerin, Victor ^{[1
]}

Schulz, Felix ^{[2
]}

Nieger, Martin ^{[1
]}

Leskelae, Markku ^{[1
]}

Repo, Timo ^{[1
]}

Rieger, Bernhard ^{[2
]}

机构：

[1] Univ Helsinki, Dept Chem, Helsinki 00014, Finland

[2] Tech Univ Munich, Wacker Lehrstuhl Makromol Chem, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 32期

关键词：

amines; boranes; hydrogen; Lewis acids; Lewis bases;

D O I：

10.1002/anie.200800935

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Divide and conquer: Metal-free systems consisting of amines and B(C6F5)3 cleave H 2 heterolytically at ambient pressure and often at room temperature. The efficient reduction of benzaldehyde by the product shown in the scheme highlights the potential of such systems for application in hydrogenation reactions. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6001 / 6003

页数：3

共 28 条

[1]

[Anonymous], 2007, ANGEW CHEM INT EDIT, DOI DOI 10.1002/ANGE.200701215

[2] B(C6F5)3-catalyzed hydrosilation of imines via silyliminium intermediates [J].