Stereoselective electrocatalytic transformation of malonate and alkylidenecyanoacetates into (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates

被引：44

作者：

Elinson, MN

Feducovich, SK

Starikova, ZA

Vereshchagin, AN

Belyakov, PA

Nikishin, GI

机构：

[1] ND Zelinskii Inst Organ Chem, Moscow 119991, Russia

[2] AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

TETRAHEDRON | 2006年 / 62卷 / 17期

基金：

俄罗斯基础研究基金会;

关键词：

electrolysis; stereoselectivity; electrocatalytic transformation; mediators; malonate; alkylidenecyanoacetates; substituted cyclopropanes;

D O I：

10.1016/j.tet.2006.02.027

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Electrolysis of malonate and alkylidenecyanoacetates in alcohols in an undivided cell in the presence of NaBr results in stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75-90% yields. (c) 2006 Published by Elsevier Ltd.

引用

收藏

页码：3989 / 3996

页数：8

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